Catalytic behaviour

 As transition elements have different oxidation states, they make good catalysts.

  • The different oxidation states (and similar energy of the d-orbitals) means they can gain or lose electron easily. This transfer of electrons can make a reaction go quicker.
  • As they have different ions, they can form a wide range of sites at which reactions can take place.

Catalysts you need to know.

1.                  Finely divided Ni in the hydrogenation of alkenes.

CH2=CH2(g) + H2 CH3CH3

                        This is used in the manufacture of margarine.

2.                  Solid V2O5 in the production of sulphuric acid

2SO2(g) + O2(g) ¾ 2SO3(g)

3.                  Finely divided Fe or Fe2O3 in the production of ammonia

N2(g) + 3H2(g) ¾ 2NH3(g)