Catalytic behaviour
As transition elements have different oxidation states, they make
good catalysts.
- The
different oxidation states (and similar energy of the d-orbitals)
means they can gain or lose electron easily. This transfer of
electrons can make a reaction go quicker.
- As
they have different ions, they can form a wide range of sites at which
reactions can take place.
Catalysts you need to know.
1.
Finely divided Ni in the hydrogenation of
alkenes.
CH2=CH2(g)
+ H2 → CH3CH3
This is used in the manufacture of margarine.
2.
Solid V2O5 in the
production of sulphuric acid
2SO2(g) + O2(g)
¾
2SO3(g)
3.
Finely divided Fe or Fe2O3
in the production of ammonia
N2(g) + 3H2(g)
¾
2NH3(g)
|